Synthesis, Characterization and Biological Studies of New Mn(II), Ni(II), Co(II), Cu(II) and Zn(II) of 2-(benzothiazol-2-yl)-N '-(2,5-dihydroxybenzylidene) acetohydrazide

被引:10
作者
El-Tabl, Abdou S. [1 ]
Shakdofa, Mohamad M. E. [2 ]
El-Seidy, Ahmed M. A. [2 ]
Al-Hakimi, Ahmed N. [3 ]
机构
[1] Menoufia Univ, Fac Sci, Dept Chem, Shibin Al Kawm, Egypt
[2] Natl Res Ctr, Dept Inorgan Chem, Giza, Egypt
[3] Ibb Univ, Fac Sci, Dept Chem, Ibb, Yemen
来源
JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE | 2011年 / 55卷 / 01期
关键词
Benzothiazol; Acetohydrazide; Complexes; Fungicidal activities; ESR spectroscopy;
D O I
10.5012/jkcs.2011.55.1.019
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New series of Mn(II), Ni(II), Co(II), Cu(II) and Zn(II) of the 2-(benzothiazol-2-yl)-N'-(2,5-dihydroxybenzylidene) acetohydrazide have been synthesized and characterized by elemental analysis, IR, UV-vis, 1 H-NMR, mass and ESR spectra, magnetic susceptibility and molar conductivity measurements. The spectral data and magnetic measurements of the complexes indicate that, the geometries are either square planar or octahedral. The biological activity of the ligand and its complexes against fungi (Aspergillus nigar and Fusarium oxysporium) were investigated. The metal complexes exhibited higher activity than both the parent ligand and the corresponding metal ion.
引用
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页码:19 / 27
页数:9
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