RARE EARTH BISMUTH TITANATES

被引：91

作者：

WOLFE, RW

NEWNHAM, RE

机构：

[1] Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1969年 / 116卷 / 06期

关键词：

D O I：

10.1149/1.2412072

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Ferroelectric compounds in the family Bi4−xRxTi3O12 (R = rare earth) have been prepared as ceramics and single crystals. The solid solution limit increases with ionic radius: xmax exceeds 2 for La3+ and Pr3+ and approaches zero for the smaller Yb3+ and Lu3+ ions. The larger rare earth ions also stabilize the paraelectric phase. The dielectric properties and crystal chemistry of the bismuth titanates are discussed with reference to related structures, and the results of preliminary optical and electrical measurements are given. © 1969, The Electrochemical Society, Inc. All rights reserved.

引用

页码：832 / &

共 12 条

[1]

AURVILLIUS B, 1949, ARKIV KEMI, V2, P463

[2]

AURVILLIUS B, 1950, ARKIV KEMI, V1, P519

[3]

AURVILLIUS B, 1949, ARK KEMI, V1, P499

[4] ELECTRICAL AND OPTICAL PROPERTIES OF FERROELECTRIC BI4TI3O12 SINGLE CRYSTALS [J].