MECHANISM OF CHEMILUMINESCENCE FROM PEROXY RADICALS

被引：96
|
作者：
KELLOGG, RE
机构：
[1] Central Research Department, Experimental Station, E. I. du Pont de Nemours and Company, Wilmington
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 20期
关键词：
D O I：
10.1021/ja01048a005
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chemiluminescence accompanying disproportionation of peroxy radicals is studied. This reaction produces triplet states specifically (T/S > 104) and with high efficiency. The low emission yield, Φc ≅ 10−8-10−10 is ascribed to quenching in the cage by the eliminated O2. © 1969, American Chemical Society. All rights reserved.
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页码：5433 / &
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