A DINUCLEAR COPPER(II) COMPLEX OF DEPROTONATED N,N'-BIS(N-PROPYLGLYCYL)-ETHYLENEDIAMINE

被引：0
|
作者：
TAHIROV, TH
LU, TH
SHU, KL
CHUNG, CS
HUANG, CC
HONG, YS
机构：
[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN
[2] CHUNG CHENG INST TECHNOL,DEPT APPL CHEM,TAHSI 33508,TAIWAN
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷
关键词：
D O I：
10.1107/S010827019300722X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title crystal of bis[mu-N,N'-bis(N-propylglycyl-kappaN)ethylenediaminato-kappaN:kappaO']bis[aquacopper(II)] diperchlorate, [Cu2(C12H25N4O2)2(H2O)2](ClO4)2, the cation exists as a dinuclear complex. Each Cu(II) ion is pentacoordinated in a distorted square-pyramid conformation: two donor N atoms of one tetradentate ligand and one N atom and one O atom of the other ligand form a slightly distorted equatorial plane and a water 0 atom occupies the axial position.
引用
收藏
页码：204 / 206
页数：3
相关论文
共 50 条
  • [31] COPPER(II) AND NICKEL(II) WITH N,N '-BIS(SALICYLIDENE)THIOSEMICARBAZIDE HETEROMETAL COMPLEX COMPOUNDS
    Panchenko, Tetiana
    Evseeva, Maria
    Ranskiy, Anatoliy
    CHEMISTRY & CHEMICAL TECHNOLOGY, 2014, 8 (03): : 243 - 248
  • [32] Chloro[N′,N′-diethyl-N,N-bis(2-pyridylmethyl)ethylenediamine-κ4N]copper(II) perchlorate
    Kani, Y
    Ohba, S
    Kunita, M
    Nishida, Y
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : e198 - e198
  • [33] A COPPER(II) COMPLEX OF THE DEPROTONATED ANION OF (2R,10R)-N,N'-DIALANYLPROPYLENEDIAMINE
    TAHIROV, TH
    LU, TH
    SHU, K
    CHUNG, CS
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 710 - 712
  • [34] BIS (N,N'-DISALICYLALETHYLENEDIAMINE)-MU-AQUODICOBALT(II) - BIS[N,N'-BIS(ORTHO-HYDROXYBENZYLIDINE)ETHYLENEDIAMINE]-MU-AQUODICOBALT(II)
    DIEHL, H
    HACH, CC
    INORGANIC SYNTHESES, 1950, 3 : 196 - 201
  • [35] (Ethylenediamine-kappa N-2,N ')bis(perchlorato-kappa O)bis(pyridine-kappa N)copper(II)
    Ourari, Ali
    Bounab, Nawel
    Bouacida, Sofiane
    Aggoun, Djouhra
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1030 - +
  • [36] COPPER(II) COMPLEXES OF N,N'-BIS-(BETA-CARBAMOYLETHYL) ETHYLENEDIAMINE IN AQUEOUS-SOLUTION
    WEI, LW
    CHAO, MS
    CHUNG, CS
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1979, 26 (04) : 145 - 151
  • [37] Bis(ethylenediamine-κ2N,N′)bis-(phenytoinato-κN)cobalt(II)
    Hu, Xi-Lan
    Xu, Xing-You
    Wang, Da-Qi
    Zhou, Yan-Qin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1470 - U2038
  • [38] Fluorescence of Zinc Complex with N,N'-Bis(5-Bromosalicylidene)Ethylenediamine
    Borisov, A. N.
    Puzyk, M. V.
    Ardasheva, L. P.
    Pak, V. N.
    OPTICS AND SPECTROSCOPY, 2017, 123 (06) : 889 - 892
  • [39] Interaction of copper(II) complex of compartmental Schiff base ligand N,N′-bis(3-hydroxysalicylidene)ethylenediamine with bovine serum albumin
    Boghaei, Davar M.
    Farvid, Shokouh S.
    Gharagozlou, Mehmaz
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 66 (03) : 650 - 655
  • [40] NICKEL(II) AND COPPER(II) COMPLEXES OF N,N'-BIS(2,4-DINITROPHENYL)ETHYLENEDIAMINE AND ITS REDUCTION PRODUCT
    SHUKLA, PR
    CHANDRA, S
    SINGH, RB
    AWASTHI, BB
    NARAIN, G
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1984, 23 (05): : 438 - 440
12345