SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES CATALYZED BY SUPPORTED AQUEOUS-PHASE CATALYSTS AND SUPPORTED HOMOGENEOUS CATALYSTS

被引：53
作者：
FACHE, E [1 ]
MERCIER, C [1 ]
PAGNIER, N [1 ]
DESPEYROUX, B [1 ]
PANSTER, P [1 ]
机构：
[1] DEGUSSA AG,W-6450 HANAU 1,GERMANY
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 79卷 / 1-3期
关键词：
HYDROGENATION; IRIDIUM; RUTHENIUM; SUPPORTED CATALYST; ALPHA; BETA-UNSATURATED ALDEHYDES;
D O I：
10.1016/0304-5102(93)85095-B
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Selective hydrogenations of different alpha,beta-unsaturated aldehydes into allylic alcohols with immobilized homogeneous catalysts are reported. Different kinds of catalysts were used: supported aqueous-phase catalysts (RuCl2(TPPTS)3/SiO2 and RuH2(TPPTS)4/SiO2) and supported homogeneous catalysts (especially phosphino-iridium catalysts like IrCl3{(C6H5)P[(CH2)3SiO3/2]2.2N[(CH2)3SiO3/2]3.2SiO2}3). Some of them are good alternatives to homogeneous catalysts since they are chemoselective, sometimes stereoselective and easy to recover.
引用
收藏
页码：117 / 131
页数：15
相关论文
共 50 条
  • [41] Highly Selective Hydrogenation of Phenol Catalyzed by Porous BN Supported Ni-Pd Catalysts
    Zhang, Lei
    Fang, Yi
    Du, Zhao
    Bi, Dandan
    Guo, Zhonglu
    Liu, Zhenya
    Huang, Yang
    Lin, Jing
    Tang, Chengchun
    CHEMISTRYSELECT, 2021, 6 (24): : 5975 - 5982
  • [42] Selective hydrogenation of crotonaldehyde over gallia and germania supported ruthenium catalysts in a gas phase
    Gebauer-Henke, E.
    Rynkowski, J.
    POLISH JOURNAL OF CHEMISTRY, 2008, 82 (1-2) : 25 - 31
  • [43] Tailoring of polymer-supported metal catalysts for selective hydrogenation
    Li, H
    He, BL
    REACTIVE & FUNCTIONAL POLYMERS, 1995, 26 (1-3) : 61 - 66
  • [44] Gas phase transfer hydrogenation of α, β- unsaturated carbonyl compounds into saturated carbonyl compounds over supported Cu catalysts
    Reddy, Saidulu K.
    Enumula, Siva Sankar
    Koppadi, Kumara Swamy
    Kamaraju, Seetha Rama Rao
    Burri, David Raju
    MOLECULAR CATALYSIS, 2020, 482
  • [45] Selective hydrogen of α, β-unsaturated ketones to α, β-unsaturated alcohols on gold-supported catalysts
    Milone, C
    Ingoglia, R
    Pistone, A
    Neri, G
    Frusteri, F
    Galvagno, S
    JOURNAL OF CATALYSIS, 2004, 222 (02) : 348 - 356
  • [46] Selective liquid-phase hydrogenation of citral over supported bimetallic Pt-Co catalysts
    Bertero, Nicolds M.
    Trasarti, Andres F.
    Moraweck, Bernard
    Borgna, Armando
    Marchi, Alberto J.
    APPLIED CATALYSIS A-GENERAL, 2009, 358 (01) : 32 - 41
  • [47] Selective Hydrogenation of Benzonitrile by Alumina-Supported Ir-Pd Catalysts
    Lopez-De Jesus, Yaritza M.
    Johnson, Caroline E.
    Monnier, John R.
    Williams, Christopher T.
    TOPICS IN CATALYSIS, 2010, 53 (15-18) : 1132 - 1137
  • [48] Particle size effects in the selective hydrogenation of cinnamaldehyde over supported palladium catalysts
    Jiang, Feng
    Cai, Jian
    Liu, Bing
    Xu, Yuebing
    Liu, Xiaohao
    RSC ADVANCES, 2016, 6 (79): : 75541 - 75551
  • [49] Platinum nanoparticles supported on ionic liquid-modified magnetic nanoparticles: Selective hydrogenation catalysts
    Abu-Reziq, Raed
    Wang, Dashan
    Post, Michael
    Alper, Howard
    ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (13) : 2145 - 2150
  • [50] Asymmetric hydrogenation of alpha,beta-unsaturated carboxylic acid esters by rhodium(I)-phosphine complexes supported on smectites
    Shimazu, S
    Ro, K
    Sento, T
    Ichikuni, N
    Uematsu, T
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 107 (1-3) : 297 - 303
12345