THE OBSERVATION OF A PB-LI BOND - SYNTHESIS, STRUCTURE AND MODEL MOLECULAR-ORBITAL (MO) CALCULATIONS ON THE MONOMERIC PH3PB-LI.(PMDETA) COMPLEX [PMDETA=(ME2NCH2CH2)2NME]

被引：32

作者：

ARMSTRONG, DR

DAVIDSON, MG

MONCRIEFF, D

STALKE, D

WRIGHT, DS

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND

[3] FLORIDA STATE UNIV,SUPERCOMP COMP RES INST,TALLAHASSEE,FL 32306

[4] INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 19期

关键词：

D O I：

10.1039/c39920001413

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound has been synthesised by the cleavage reaction of Ph3Pb-PbPh3 with Bu(n)Li and has been shown to have a monomeric Pb-Li bonded structure in the solid state; ab initio calculations have been used to probe the nature of the early main group metal/heavy p block metal bonding involved.

引用

页码：1413 / 1415

页数：3

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