THE OBSERVATION OF A PB-LI BOND - SYNTHESIS, STRUCTURE AND MODEL MOLECULAR-ORBITAL (MO) CALCULATIONS ON THE MONOMERIC PH3PB-LI.(PMDETA) COMPLEX [PMDETA=(ME2NCH2CH2)2NME]

被引：32
作者：
ARMSTRONG, DR
DAVIDSON, MG
MONCRIEFF, D
STALKE, D
WRIGHT, DS
机构：
[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
[2] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND
[3] FLORIDA STATE UNIV,SUPERCOMP COMP RES INST,TALLAHASSEE,FL 32306
[4] INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 19期
关键词：
D O I：
10.1039/c39920001413
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound has been synthesised by the cleavage reaction of Ph3Pb-PbPh3 with Bu(n)Li and has been shown to have a monomeric Pb-Li bonded structure in the solid state; ab initio calculations have been used to probe the nature of the early main group metal/heavy p block metal bonding involved.
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页码：1413 / 1415
页数：3
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