Crystal structure of tris(N-methylsalicylaldiminato-kappa N-2,O)vanadium(III)

被引：1

作者：

Hilbert, Jessica ^{[1
]}

Kabus, Sven ^{[1
]}

Naether, Christian ^{[1
]}

Bensch, Wolfgang ^{[1
]}

机构：

[1] Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; vanadium(III); N-methylsalicylaldiminate;

D O I：

10.1107/S2056989015021453

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of the title complex, [V(C8H8NO)(3)], comprises neutral and discrete complexes, in which the V-III cation is coordinated by three anionic N-methylalicylaldiminate ligands within a slightly distorted mer-N3O3 octahedral geometry. In the crystal structure, the molecules are linked via C-H center dot center dot center dot O hydrogen bonds into supramolecular chains that extend along the c axis.

引用

页码：M225 / U203

页数：9

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