Crystal structure of tris(N-methylsalicylaldiminato-kappa N-2,O)vanadium(III)

被引：1
|
作者：
Hilbert, Jessica [1 ]
Kabus, Sven [1 ]
Naether, Christian [1 ]
Bensch, Wolfgang [1 ]
机构：
[1] Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; vanadium(III); N-methylsalicylaldiminate;
D O I：
10.1107/S2056989015021453
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title complex, [V(C8H8NO)(3)], comprises neutral and discrete complexes, in which the V-III cation is coordinated by three anionic N-methylalicylaldiminate ligands within a slightly distorted mer-N3O3 octahedral geometry. In the crystal structure, the molecules are linked via C-H center dot center dot center dot O hydrogen bonds into supramolecular chains that extend along the c axis.
引用
收藏
页码：M225 / U203
页数：9
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