NAMO6CL13 - CRYSTAL-CHEMISTRY OF MOLYBDENUM(II) HALIDES

被引：11

作者：

BOSCHEN, S

KELLER, HL

机构：

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1991年 / 196卷 / 1-4期

关键词：

SODIUM OCTA-MU-3-CHLORO-PENTACHLORO-OCTAHEDRO-HEXAMOLYBDATE(II); CRYSTAL STRUCTURE; MO6CL14-GROUP; IONIC-CONDUCTIVITY;

D O I：

10.1524/zkri.1991.196.1-4.159

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of NaMo6Cl13 was solved in the triclinic space group P 1BAR (No. 2) by X-ray crystal structure analysis (a = 8.962(5) angstrom, b = 9.089(5) angstrom, c = 14.022(9) angstrom, alpha = 96.51(3)-degrees, beta = 101.73(2)-degrees, gamma = 115.13(2)-degrees and Z = 2). The compound was prepared from a mixture of sodium chloride and molybdenum(II) chloride (1:6) at a temperature of 850-degrees-C. The structure is based on [Mo6Cl8i]Cl4(a)Cl2/2a-a groups which form a onedimensional arrangement. Sodium is surrounded by four chlorine atoms forming a strongly distorted tetrahedron. The structure and physical properties are discussed.

引用

页码：159 / 168

页数：10

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