SOLUBILITY OF GASEOUS HYDROCARBONS AND THE HYDROPHOBIC EFFECT IN AQUEOUS-SOLUTIONS OF HEXAMETHYLENETETRAMINE

被引：18
|
作者：
BARONE, G
CASTRONUOVO, G
DELLAVOLPE, C
ELIA, V
GRASSI, L
机构：
[1] Istituto Chimico, University of Naples
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 21期
关键词：
D O I：
10.1021/j100484a005
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The solubilities of methane and ethane in aqueous solutions of hexamethylenetetramine have been studied in order to evaluate the hydrophobic effect according to the Ben-Naim model. The effect of hexamethylonetetramine, a molecule extensively hydrated, results in a reinforcing of hydrophobic interactions; this fact is related to the poor effectiveness of hexamethylenetetramine in the denaturing processes of biomacromolecules. © 1979 American Chemical Society.
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页码：2703 / 2706
页数：4
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