MICROWAVE MODULATED SATURATION SPECTROSCOPY

被引：9
作者：
KASPER, JVV
LOWE, RS
CURL, RF
机构：
[1] Department of Chemistry, Rice University, Houston
[2] Department of Chemistry, University of California at Los Angeles, Los Angeles
[3] Herzberg Institute of Astrophysics, Ottawa
来源：
JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 07期
关键词：
D O I：
10.1063/1.437920
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
By combining intermodulated fluorescence saturation spectroscopy with microwave optical double resonance, a new experimental laser spectroscopy technique, microwave modulated saturation (MMS) spectroscopy, has been developed. This technique has been used to simplify the complex 14N and proton hyperfine structure observed by saturation spectroscopy of NH 2[I10, J = 3/2←(-220, J = 5/2, A 2A1π(0,10,0)← X2B1(OAO)], This simplification made possible a complete assignment of the hyperfine energy levels. A population model of these experiments has been developed. © 1979 American Institute of Physics.
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页码：3350 / 3355
页数：6
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