SPECTROSCOPIC ANALYSIS OF ION-IRRADIATED POLY(PHENYLENE SULFIDE)

被引：15

作者：

SCHOCH, KF

BARTKO, J

机构：

[1] Westinghouse Research &, Development Cent, Pittsburgh, PA,, USA, Westinghouse Research & Development Cent, Pittsburgh, PA, USA

来源：

POLYMER | 1987年 / 28卷 / 04期

关键词：

CALORIMETRY - MICROSCOPIC EXAMINATION - PLASTICS FILMS - Radiation Effects - SPECTROSCOPY; INFRARED;

D O I：

10.1016/0032-3861(87)90469-1

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Films of poly(phenylene sulphide) have been irradiated with high energy ions to produce electrically conductive materials. The ions used have been 323 kev Li, 5. 6 Mev F, and 50 Mev I. Conductivities between 5. 7 multiplied by 10** minus **5 S cm** minus **1 and 0. 7 S cm** minus **1 have been observed depending on irradiation conditions. The irradiated polymers have been characterized by infra-red and e. p. r. spectroscopy as well as differential scanning calorimetry (d. s. c. ), X-ray diffraction, and scanning electron microscopy. Possible explanations are discussed. Scanning electron microscopy shows evidence of gas evolution during irradiation.

引用

页码：556 / 562

页数：7

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