THERMAL-CHANGE OF SNI2 THIN-FILMS .1. THERMOGRAVIMETRY

被引：16

作者：

SAWADA, Y

SUZUKI, M

机构：

[1] Department of Industrial Chemistry, Faculty of Engineering, Tokyo Institute of Polytechnics, Atsugi-shi, Kanagawa, 243-02

来源：

THERMOCHIMICA ACTA | 1994年 / 232卷 / 01期

关键词：

D O I：

10.1016/0040-6031(94)80042-1

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermal change of tin iodide (SnI2) evaporated film as-deposited on a glass substrate has been successfully detected by TG (heating rate, 10-degrees-C/min-1) film mass about 0.5 mg, film area about 2 cm2. A mass loss at 260-420-degrees-C in an argon flow is attributed to the evaporation of SnI2. A mass loss at 180-290-degrees-C in an air flow is interpreted as oxidation of SnI2 to form SnI4 vapor and tin oxide. The TG-DTA for SnI2 and SnI4 powders in a nitrogen flow (heating rate, 10-degrees-C min have been performed to understand the thermal change of SnI2 thin films; an endothermic phenomenon without mass change attributed to melting at 319 and 144-degrees-C and an endothermic mass loss attributed to evaporation at 300-460 and 85-190-degrees-C were observed for SnI2 and SnI4 powders, respectively. A small mass loss (about 7%) at 85-150-degrees-C for SnI2 powders is attributed to the evaporation of SnI4 impurity.

引用

页码：29 / 36

页数：8

共 13 条

[1]

BARIN I, 1973, THERMOCHEMICAL PROPE, P584

[2] APPLICATIONS OF THERMOANALYTICAL METHODS TO THE STUDY OF THIN-FILMS [J].

GALLAGHER, PK .

JOURNAL OF THERMAL ANALYSIS, 1992, 38 (1-2) :17-26

[3] THE KINETICS OF THE PHOTOLYSIS OF THIN-FILMS OF TIN DIIODIDE [J].

GREEN, M ;

KUKU, TA .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1983, 44 (10) :999-1008

[4] PHYSICAL-PROPERTIES OF THIN SNO2 AND SNO2-SB FILMS OBTAINED BY A PHOTOLYTIC METHOD [J].

KUKU, TA .

THIN SOLID FILMS, 1986, 142 (02) :241-250

[5] PHOTOCHEMICAL FABRICATION OF SNO2 AND TIN MICROPATTERNS FROM SNI2 THIN-FILMS [J].

KUKU, TA ;

GREEN, M .

THIN SOLID FILMS, 1986, 144 (02) :L119-L120

[6] DSC OF AS-DEPOSITED THIN-FILMS DIP-COATED ON THE SUBSTRATE - THERMAL-CHANGE OF INDIUM (III) 2-ETHYLHEXANOATE TO FORM IN2O3 THIN-FILMS [J].

SAWADA, Y ;

OMIKA, K ;

ITO, Y ;

MUTA, F ;

MOMOTA, M .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1993, 40 (03) :1145-1150

[7] THERMAL-OXIDATION OF INDIUM NITRIDE FILMS [J].

SAWADA, Y ;

HASHIMOTO, A .

THERMOCHIMICA ACTA, 1994, 231 :307-315

[8]

SAWADA Y, 1989, NETSU SOKUTEI, V16, P185

[9]

WEAST RC, 1970, CRC HDB CHEM PHYSICS, pB148

[10]

ZHAMSKAYA NN, 1977, RUSS J PHYS CHEM, V51, P1007

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