PREPARATION AND PROPERTIES OF ALKYLBIS(DIMETHYLGLYOXIMATO)RHODIUM(III) COMPLEXES

被引：24
作者：
GIESE, B
HARTUNG, J
KESSELHEIM, C
LINDNER, HJ
SVOBODA, I
机构：
[1] UNIV BASEL,INST ORGAN CHEM,CH-4056 BASEL,SWITZERLAND
[2] TH DARMSTADT,INST ORGAN CHEM,W-6100 DARMSTADT,GERMANY
[3] TH DARMSTADT,INST MAT FORSCH,W-6100 DARMSTADT,GERMANY
来源：
CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 05期
关键词：
ALKYLRHODOXIMES; RADICALS; ALKYL; HALOGEN ABSTRACTION; CARBON CARBON BOND FORMATION; STEREOCHEMISTRY; PHOTOREACTIONS;
D O I：
10.1002/cber.19931260520
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Primary, secondary, and tertiary alkylrhodoximes 1 were prepared from alkyl bromides and tosylates 4 and the trans-dichlororhodium complex 3. X-ray crystallography of the previously unknown tert-butylrhodoxime 1k reveals structural features of this tert-sigma-alkylrhodium compound. Photochemical homolytic cleavage of the Rh-C bond in alkylrhodoximes 1 only occurs in the presence of efficient radical traps which allow further mechanistic studies.
引用
收藏
页码：1193 / 1200
页数：8
相关论文
共 50 条
  • [41] Substituent effects in the preparation of quinazolinones by rhodium-catalysed hydroformylation reactions of 2-(allylamino)benzamides
    Campi, EM
    Jackson, WR
    Trnacek, AE
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1997, 50 (10) : 1031 - 1034
  • [42] Syntheses, structures, and spectroscopic properties of cobalt(III) complexes containing 3-or 4-pyridyl-substituted nitronyl and imino nitroxide ligands
    Ogita, M
    Yamamoto, Y
    Suzuki, T
    Kaizaki, S
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2002, (04) : 886 - 894
  • [43] Differential Anticancer Activities of the Geometric Isomers of Dinuclear Iridium(III) Complexes
    Pandrala, Mallesh
    Sundaraneedi, Madhu K.
    Ammit, Alaina J.
    Woodward, Clifford E.
    Wallace, Lynne
    Keene, F. Richard
    Collins, J. Grant
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (34) : 5694 - 5701
  • [44] Rh(I) and Organo-Rh(III) Complexes of meso-Triarylbiphenylcorrole
    Chitranshi, Sangya
    Adinarayana, B.
    Das, Mainak
    Anila, Sebastian
    Suresh, Cherumuttathu H.
    Srinivasan, A. .
    INORGANIC CHEMISTRY, 2023, 62 (01) : 336 - 341
  • [45] Bioinspired Five-Coordinate Iron(III) Complexes for Stabilization of Phenoxyl Radicals
    Allard, Marco M.
    Sonk, Jason A.
    Heeg, Mary Jane
    McGarvey, Bruce R.
    Schlegel, H. Bernhard
    Verani, Claudio N.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (13) : 3178 - 3182
  • [46] Ag(I) and Au(III) Mercaptobenzothiazole complexes induced apoptotic cell death
    Sherine, Jositta
    Upadhyay, Arun
    Mishra, Amit
    Kumar, Deepak
    Pal, Samanwita
    Harinipriya, S.
    SCIENTIFIC REPORTS, 2019, 9 (1)
  • [47] Heterobimetallic Complexes of Rhodium Dibenzotetramethylaza[14]annulene [(tmtaa)Rh-M]: Formation, Structures, and Bond Dissociation Energetics
    Imler, Gregory H.
    Peters, Garvin M.
    Zdilla, Michael J.
    Wayland, Bradford B.
    INORGANIC CHEMISTRY, 2015, 54 (01) : 273 - 279
  • [48] Some novel manganese(III) porphyrins with catalytic properties
    Anand, Niharika
    Yadava, Sudha
    JOURNAL OF COORDINATION CHEMISTRY, 2018, 71 (19) : 3090 - 3098
  • [49] Rh(III) and Ir(III)Cp* Complexes Provide Complementary Regioselectivity Profiles in Intermolecular Allylic C-H Amidation Reactions
    Burman, Jacob S.
    Harris, Robert J.
    Farr, Caitlin M. B.
    Bacsa, John
    Blakey, Simon B.
    ACS CATALYSIS, 2019, 9 (06): : 5474 - 5479
  • [50] Density functional theory calculated data of the iodomethane oxidative addition to oligothiophene-containing rhodium complexes - Importance of dispersion correction
    Mateyise, Nandisiwe Ghandi Sibongile
    Conradie, Jeanet
    Conradie, Marrigje M.
    DATA IN BRIEF, 2021, 35
12345