PREPARATION AND PROPERTIES OF ALKYLBIS(DIMETHYLGLYOXIMATO)RHODIUM(III) COMPLEXES

被引：24
作者：
GIESE, B
HARTUNG, J
KESSELHEIM, C
LINDNER, HJ
SVOBODA, I
机构：
[1] UNIV BASEL,INST ORGAN CHEM,CH-4056 BASEL,SWITZERLAND
[2] TH DARMSTADT,INST ORGAN CHEM,W-6100 DARMSTADT,GERMANY
[3] TH DARMSTADT,INST MAT FORSCH,W-6100 DARMSTADT,GERMANY
来源：
CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 05期
关键词：
ALKYLRHODOXIMES; RADICALS; ALKYL; HALOGEN ABSTRACTION; CARBON CARBON BOND FORMATION; STEREOCHEMISTRY; PHOTOREACTIONS;
D O I：
10.1002/cber.19931260520
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Primary, secondary, and tertiary alkylrhodoximes 1 were prepared from alkyl bromides and tosylates 4 and the trans-dichlororhodium complex 3. X-ray crystallography of the previously unknown tert-butylrhodoxime 1k reveals structural features of this tert-sigma-alkylrhodium compound. Photochemical homolytic cleavage of the Rh-C bond in alkylrhodoximes 1 only occurs in the presence of efficient radical traps which allow further mechanistic studies.
引用
收藏
页码：1193 / 1200
页数：8
相关论文
共 50 条
  • [21] Antiproliferative, DNA binding, and cleavage properties of dinuclear Co(III) complexes containing the bioactive quinizarin ligand
    Hana Crlikova
    Hana Kostrhunova
    Jitka Pracharova
    Máté Kozsup
    Sándor Nagy
    Péter Buglyó
    Viktor Brabec
    Jana Kasparkova
    JBIC Journal of Biological Inorganic Chemistry, 2020, 25 : 339 - 350
  • [22] Photoinduced evolution of optical properties and compositions of methoxyphenols by Fe(III)-carboxylates complexes in atmospheric aqueous phase
    Yan, Ran
    Yang, Wangjin
    You, Di
    Yang, Hongxing
    Han, Chong
    CHEMOSPHERE, 2022, 295
  • [23] Mechanistic insight into formaldehyde hydroformylation catalyzed by rhodium complexes: A theoretical and experimental study
    Dai, Weikang
    Li, Maoshuai
    Wei, Jie
    Yang, Qi
    Feng, Yi
    Yang, Cheng
    Yang, Wanxin
    Wang, Mei-Yan
    Ma, Xinbin
    JOURNAL OF CATALYSIS, 2021, 399 : 41 - 51
  • [24] Pentamethylcyclopentadienyl-Supported Cerocene(III) Complexes
    Schneider, David
    Anwander, Reiner
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (08) : 1180 - 1188
  • [25] Crystal structures and stereochemical properties of lanthanide(III) complexes with ethylenediamine-N,N,N′,N′-tetraacetate
    Sakagami, N
    Yamada, Y
    Konno, T
    Okamoto, K
    INORGANICA CHIMICA ACTA, 1999, 288 (01) : 7 - 16
  • [26] Influence of electronic and steric effects of substituted ligands coordinated to Ir(III) complexes on the solution processed OLED properties
    Mroz, Wojciech
    Ragni, Roberta
    Galeotti, Francesco
    Mesto, Ernesto
    Botta, Chiara
    De Cola, Luisa
    Farinola, Gianluca Maria
    Giovanella, Umberto
    JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (28) : 7506 - 7512
  • [27] Proton induced coupling reactions in dinuclear σ-alkynyl-μ-methylene-rhodium complexes
    Castro, A
    Maitlis, PM
    Turner, ML
    Mann, BE
    Adams, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 663 (1-2) : 145 - 150
  • [28] Exploring Dinuclear Titanium Complexes in Titanium(III) Catalysis
    Unkrig-Bau, Michael A.
    Leijendekker, Sara L.
    Streuff, Jan
    CHEMCATCHEM, 2025, 17 (01)
  • [29] Zeolite- and MgO-supported rhodium complexes and rhodium clusters: Tuning catalytic properties to control carbon-carbon vs. carbon-hydrogen bond formation reactions of ethene in the presence of H2
    Serna, Pedro
    Gates, Bruce C.
    JOURNAL OF CATALYSIS, 2013, 308 : 201 - 212
  • [30] Recent Development of Bis-Cyclometalated Chiral-at-Iridium and Rhodium Complexes for Asymmetric Catalysis
    Dey, Purusattam
    Rai, Pramod
    Maji, Biplab
    ACS ORGANIC & INORGANIC AU, 2022, 2 (02): : 99 - 125
12345