STRUCTURAL INVESTIGATIONS OF TRANSITION-METAL (II) TETRACYANONICKELATE COMPLEXES OF 3-CHLOROPYRIDINE USING FOURIER TRANSFORM-INFRARED AND LASER RAMAN-SPECTROSCOPY

被引：11

作者：

AKYUZ, S

AKYUZ, T

DAVIES, JED

机构：

[1] MINERAL RES & EXPLORAT INST,SPECTROCHEM LAB,ANKARA 06520,TURKEY

[2] UNIV LANCASTER,INST ENVIRONM & BIOL SCI,DIV ENVIRONM SCI,LANCASTER LA1 4YQ,ENGLAND

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1992年 / 265卷 / 1-2期

关键词：

D O I：

10.1016/0022-2860(92)80240-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN), (where M = Mn, Fe, Ni, Zn or Cd; L = 3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two-dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn almost-equal-to Cd < Fe < Zn < Ni.

引用

页码：85 / 91

页数：7

共 15 条

[11] STRUCTURE OF MOLECULAR COMPOUNDS .10. CRYSTAL STRUCTURE OF THE COMPOUND OF BENZENE WITH AN AMMONIA NICKEL CYANIDE COMPLEX [J].

RAYNER, JH ;

POWELL, HM .

JOURNAL OF THE CHEMICAL SOCIETY, 1952, (FEB) :319-328

[12] ON THE PREPARATION OF 5-COORDINATE (3-CHLOROPYRIDINE)(PORPHINATO)IRON(III) COMPLEXES [J].

SCHEIDT, WR ;

GEIGER, DK ;

LEE, YJ ;

REED, CA ;

LANG, G .

INORGANIC CHEMISTRY, 1987, 26 (07) :1039-1045

[13] MOLECULAR-FORCE FIELD OF PYRIDINE AND ITS APPLICATION TO PYRIDINE-METAL COMPLEXES [J].

SUZUKI, S ;

ORVILLETHOMAS, WJ .

JOURNAL OF MOLECULAR STRUCTURE, 1977, 37 (02) :321-327

[14] CRYSTAL-STRUCTURE OF DIPYRIDINECADMIUM TETRACYANONICKELATE, CD(C5H5N)2NI(CN)4 [J].

ULKU, D .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1975, 142 (3-4) :271-280

[15] The normal modes and frequencies of vibration of the regular plane hexagon model of the benzene molecule [J].

Wilson, EB .

PHYSICAL REVIEW, 1934, 45 (10) :0706-0714

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