STRUCTURAL INVESTIGATIONS OF TRANSITION-METAL (II) TETRACYANONICKELATE COMPLEXES OF 3-CHLOROPYRIDINE USING FOURIER TRANSFORM-INFRARED AND LASER RAMAN-SPECTROSCOPY

被引：11

作者：

AKYUZ, S

AKYUZ, T

DAVIES, JED

机构：

[1] MINERAL RES & EXPLORAT INST,SPECTROCHEM LAB,ANKARA 06520,TURKEY

[2] UNIV LANCASTER,INST ENVIRONM & BIOL SCI,DIV ENVIRONM SCI,LANCASTER LA1 4YQ,ENGLAND

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1992年 / 265卷 / 1-2期

关键词：

D O I：

10.1016/0022-2860(92)80240-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The FT-IR and laser-Raman spectra of five new complexes of the formula ML2Ni(CN), (where M = Mn, Fe, Ni, Zn or Cd; L = 3-chloropyridine) are reported. The complexes are shown to have a structure consisting of two-dimensional polymeric layers formed with Ni(CN)4 ions bridged by ML2 cations. For a given series of isomorphous complexes, the effects of metal ligand bond formation on the ligand vibrational modes are examined and the metal-sensitivity sequence of the ligand frequencies is found to be Mn almost-equal-to Cd < Fe < Zn < Ni.

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页码：85 / 91

页数：7

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