rac-4-Chloro-2-[({2-[(3-chloro-6-hydroxy-2,4-dimethylbenzyl)(methyl)amino] propyl}(methyl)-amino)methyl]-3,5-dimethylphenol

被引:0
作者
Rivera, Augusto [1 ]
Pacheco, Dency Jose [1 ]
Rios-Motta, Jaime [1 ]
Maldonado, Mauricio [1 ]
Bolte, Michael [1 ]
机构
[1] Univ Nacl Colombia, Fac Ciencias, Dept Quim, Cra 30 45-03, Bogota 111321, Colombia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
D O I
10.1107/S1600536812039694
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C23H32Cl2N2O2, a potential chiral ligand for coordination chemistry, was prepared by a two-step reaction. The molecule is located on a crystallographic centre of inversion. As a result, the methyl group bonded to the methylene group is disordered over two equally occupied positions, sharing the same site as the H atom of the chiral C atom. As a further consequence of the crystallographic centrosymmetry, the 1,2-diaminopropane unit adopts an antiperiplanar conformation and the two benzene rings are coplanar. The central chain is in an all-trans arrangement. An intramolecular O-H center dot center dot center dot N hydrogen bond makes an S(6) ring motif. A C-H center dot center dot center dot pi interaction links the molecules into one-dimensional chains along the [001] direction.
引用
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页码:O2997 / +
页数:7
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