C59N+ AND C69N+ - ISOELECTRONIC HETEROANALOGUES OF C-60 AND C-70

被引：133

作者：

LAMPARTH, I ^{[1
]}

NUBER, B ^{[1
]}

SCHICK, G ^{[1
]}

SKIEBE, A ^{[1
]}

GROSSER, T ^{[1
]}

HIRSCH, A ^{[1
]}

机构：

[1] UNIV KARLSRUHE,INST ORGAN CHEM,D-76131 KARLSRUHE,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 20期

关键词：

FULLERENES; HETEROFULLERENES; MASS SPECTROMETRY;

D O I：

10.1002/anie.199522571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fragmentation reactions in the mass spectrometer were used to generate the first characterized nitrogen heterofullerene ions C59N+ and C69N+ from regioselectively synthesized oligoiminofullerenes. During this process one carbon atom in the fullerene core is removed and replaced with a nitrogen atom. C59N+ (shown on the right) has almost the same structure as the isoelectronic C60. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2257 / 2259

页数：3

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