Bis[2-(2-hydroxymethyl) pyridine-kappa N-2,O](pivalato-kappa O) copper(II)

被引：4
|
作者：
Shaikh, M. Mobin [1 ]
Mishra, Veenu [1 ]
Ram, Priti [1 ]
Birla, Anil [1 ]
机构：
[1] IIT Indore, Sch Basic Sci, Discipline Chem, Indore 452017, Madhya Pradesh, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 15.6; mean σ(C-C) = 0.004 Å; R factor = 0.040; single-crystal X-ray study; T = 150 K; wR factor = 0.119;
D O I：
10.1107/S1600536812030917
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the centrosymmetric title complex, [Cu(C5H9O2)(2)(C6H7NO)(2)], has the Cu-II atom on a centre of inversion. The CuII atom is six-coordinate with a distorted octahedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl) pyridine ligands and two carboxylate O atoms from two monodentate pivalate ions. The crystal packing is stabilized by intermolecular C-H ... O and intramolecular O-H ... O hydrogen-bond interactions.
引用
收藏
页码：M1055 / +
页数：9
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