INDUCTIVELY-COUPLED-PLASMA MASS SPECTROMETRY;
ONLINE PRECONCENTRATION;
DOWEX;
1-X8;
RESIN;
ARSENIC;
SELENIUM;
WATER SAMPLES;
D O I:
10.1002/jccs.199400018
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Utilisation of a miniature anion-exchanger preconcentration column of Dowex 1-X8 to increase the sensitivity for As and Se determinations by inductively-coupled-plasma mass spectrometry (ICP-MS) is described. The ion signal was enhanced were 15 fold for As and 20 fold for Se. The multielement detection limits were 2 ppt (ng/L) and 33 ppt for As and Se, respectively. This flow injection ICP-MS method was applied to the determination of trace levels of arsenic and selenium in riverine reference material SLRS-2 and spring water samples.