THE CRYSTAL-STRUCTURE OF 2,5-DICHLORO-3-METHOXY-6-(1'-TRIPHENYLPHOSPHONIO-CYCLOPENTADIEN-3-YL)-P-BENZOQUINONE

被引：2

作者：

HALL, CD

SHERIDAN, A

SHEK, L

PARKINS, AW

NYBURG, SC

机构：

[1] Department of Chemistry, King's College, Strand

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1992年 / 69卷 / 1-2期

关键词：

TRIPHENYLPHOSPHINO CYCLOPENTADIENIDE; QUINONE DERIVATIVE; X-RAY CRYSTALLOGRAPHY; CHLORANIL;

D O I：

10.1080/10426509208036866

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A single crystal X-ray diffraction study confirms that the reaction of triphenylphosphonio cyclopenta-dienide 1 with 3-methoxy-2, 5, 6-trichloro-p-benzoquinone 4 gives a product 5 with the cyclopentadiene ring substituted in position 3 and the chlorine atoms of the quinone ring replaced at positions 3 and 6. This data confirms the prediction of earlier multinuclear 2D nmr data on the reaction of 1 with chloranil. © 1992, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：167 / 172

页数：6

共 44 条

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