THE CRYSTAL-STRUCTURE OF 2,5-DICHLORO-3-METHOXY-6-(1'-TRIPHENYLPHOSPHONIO-CYCLOPENTADIEN-3-YL)-P-BENZOQUINONE

被引：2
作者：
HALL, CD
SHERIDAN, A
SHEK, L
PARKINS, AW
NYBURG, SC
机构：
[1] Department of Chemistry, King's College, Strand
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1992年 / 69卷 / 1-2期
关键词：
TRIPHENYLPHOSPHINO CYCLOPENTADIENIDE; QUINONE DERIVATIVE; X-RAY CRYSTALLOGRAPHY; CHLORANIL;
D O I：
10.1080/10426509208036866
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A single crystal X-ray diffraction study confirms that the reaction of triphenylphosphonio cyclopenta-dienide 1 with 3-methoxy-2, 5, 6-trichloro-p-benzoquinone 4 gives a product 5 with the cyclopentadiene ring substituted in position 3 and the chlorine atoms of the quinone ring replaced at positions 3 and 6. This data confirms the prediction of earlier multinuclear 2D nmr data on the reaction of 1 with chloranil. © 1992, Taylor & Francis Group, LLC. All rights reserved.
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收藏
页码：167 / 172
页数：6
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