PHOTOCATALYTIC OXIDATION OF MULTIFUNCTIONAL ORGANIC-MOLECULES - THE EFFECT OF AN INTRAMOLECULAR ARYL THIOETHER GROUP ON THE SEMICONDUCTOR-MEDIATED OXIDATION DEHYDROGENATION OF A PRIMARY ALIPHATIC ALCOHOL

被引：29

作者：

FOX, MA

ABDELWAHAB, AA

机构：

[1] Department of Chemistry University of Texas at Austin, Austin

来源：

JOURNAL OF CATALYSIS | 1990年 / 126卷 / 02期

关键词：

D O I：

10.1016/0021-9517(90)90035-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A remote thiophenyl group retards the TiO2-mediated photocatalytic oxidation of the alcohol group in 4-thiophenyl-l-butanol. Model studies implicate intramolecular bridging in the adsorbed cation radical and/or hole trapping by sulfur in the primary oxidative photoprocess at the photocatalyst-liquid interface. © 1990.

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页码：693 / 696

页数：4

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