SYNTHESIS OF ALKYLENE BRIDGED METAL-COMPLEXES AFTER CATIONIC ALKYLATION WITH ALKANDIYLBIS(TRIFLUOROMETHANESULFONATES)

被引：17
|
作者：
LINDNER, E
PABEL, M
EICHELE, K
机构：
[1] Institut für Anorganische Chemie der Universität, D-7400 Tübingen 1
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 386卷 / 02期
关键词：
D O I：
10.1016/0022-328X(90)85243-R
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrocarbon-bridged metal complexes (OC)5M(CH2)nM(CO)5 (1a,2a,2b) (M = Mn, n = 2: (1a); M = Re, n = 2: (2a), n = 3: (2b)) are obtained by reaction in dimethyl ether of the bistriflates Y(CH2)nY (Y = F3CSO2O) with the carbonyl metalates [M(CO)5]-. According to 1H NMR spectroscopic investigations, the favoured structure of 2b in solution is the conformer with C2v symmetry. © 1990.
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页码：187 / 194
页数：8
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