GAS-PHASE THERMOCHEMISTRY OF THE GROUP-3 DIOXIDES - SCO2, YO2 AND LAO2

被引：62
作者：
CLEMMER, DE
DALLESKA, NF
ARMENTROUT, PB
机构：
[1] Department of Chemistry, University of Utah, Salt Lake City
来源：
CHEMICAL PHYSICS LETTERS | 1992年 / 190卷 / 3-4期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0009-2614(92)85336-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Gas-phase ScO2, YO2, LaO2 and the singly charged cations of these species are formed in endothermic reactions between MO+ (M = Sc, Y, and La) and NO2 in a guided ion beam mass spectrometer. The cross sections of these reactions are measured as a function of kinetic energy and are interpreted to give the following 0 K bond energies (in eV): D0(OSc-O) = 3.95 +/- 0.33, D0(OY-O) = 4.14 +/- 0.22, D0(OLa-O) = 4.20 +/- 0.33, D0(OSc+-O) = 1.72 +/- 0.19, D0(OY+-O) = 1.76 +/- 0.16, and D0(OLa+-O) = 0.99 +/- 0.3l. Values for the MO2 ionization energies (in eV) are determined to be IE(SCO2) = 8.66 +/- 0.20, IE(YO2) = 8.23 +/- 0.16 and IE(LaO2) = 8.11 +/- 0.35. The differences between these values and estimates in the literature are discussed by considering the nature of the bonding in MO2 and MO2+.
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页码：259 / 265
页数：7
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