LITHIUM COMPLEXES OF 1,2-NAPHTHAQUINONE MONOOXIMES - THE X-RAY CRYSTAL-STRUCTURE OF (1,2-NAPHTHAQUINONE-1-OXIME)(1,2-NAPHTHAQUINONE-1-OXIMATO)LITHIUM(I).ETHANOL

被引：8
|
作者：
CHARALAMBOUS, J
FOGG, PGT
GAGANATSOU, P
HENDRICK, K
机构：
[1] School of Applied Chemistry, University of North London, London, N7 8DB, Holloway Road
来源：
POLYHEDRON | 1993年 / 12卷 / 08期
关键词：
D O I：
10.1016/S0277-5387(00)81540-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexes Li(1-nqo).1/2EtOH, Li(1-nqo)(1-nqoH).EtOH (1-nqoH = 1,2-naphthaquinone-1-oxime), and Li(2-nqo).1/2EtOH, Li(2-nqo)(2-nqoH).EtOH (2-nqoH = 1,2-naphthaquinone-2-oxime), were prepared by the interaction of the quinone oxime with lithium hydroxide. The structure of Li(1-nqo)(1-nqoH).EtOH was determined by single-crystal X-ray diffraction techniques. The lithium atom is penta-coordinated in a distorted square pyramidal environment.
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页码：879 / 882
页数：4
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