DIRECT MEASUREMENT OF INTRA-MOLECULAR HYDROPHOBIC INTERACTIONS

被引：35

作者：

BENNAIM, A

WILF, J

机构：

[1] Department of Physical Chemistry, Hebrew University of Jerusalem, Jerusalem

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 02期

关键词：

D O I：

10.1063/1.437508

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A theoretical argument is used to suggest a new method of processing experimental results to obtain information on pairwise hydrophobic interactions. The experimental data consist of measurements of solubilities and partition coefficients of some alkylbenzene molecules in water and in n-hexane. From these data one may extract information on the intramolecular hydrophobic interactions, i.e., interaction between two alkyl groups attached to a backbone" molecule. Some preliminary results are reported and interpreted. © 1979 American Institute of Physics."

引用

页码：771 / 777

页数：7

共 9 条

[1]

Ben-Naim A., 1974, WATER AQUEOUS SOLUTI

[2] STATISTICAL MECHANICAL STUDY OF HYDROPHOBIC INTERACTION .1. INTERACTION BETWEEN 2 IDENTICAL NONPOLAR SOLUTE PARTICLES [J].