VOLUMETRIC BEHAVIOR OF AN ISOMERIC AND BRANCHED ALCOHOLS WITH 1,2-DICHLOROETHANE

被引：1
|
作者：
BABU, KR
GOVINDAPPA, J
VENKATESWARLU, P
RAMAN, GK
机构：
[1] Department of Chemistry, College of Engineering, Sri Venkateswara University
来源：
PHYSICS AND CHEMISTRY OF LIQUIDS | 1990年 / 21卷 / 01期
关键词：
excess volumes; Hydrogen bonds;
D O I：
10.1080/00319109008028460
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Excess volumes (VE) for the binary mixtures of 1, 2-Dichloroethane with i-propanol, i-butanol, secbutanol, tert-butanol, i-pentanol, i-hexanol and cyclohexanol have been determined at 303.15 K, by dilatometric method over the entire range of composition. Values of VEare positive over the whole mole fraction range studied. Results are explained in terms of break up of hydrogen bonds, interstitial accommodation of 1, 2-dichloroethane in alcohol aggregates and possible hydrogen bond interaction of the type Cl…. H — O between unlike molecules. © 1990, Taylor & Francis Group, LLC. All rights reserved.
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页码：23 / 27
页数：5
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