CRYSTALLINE ENVIRONMENT OF FE3+ IONS IN HIGHLY MG-DOPED LINBO3 CRYSTAL

被引:0
|
作者
ZHENG, WC [1 ]
机构
[1] ACAD SINICA,INT CTR MAT PHYS,SHENYANG 110015,PEOPLES R CHINA
来源
RADIATION EFFECTS AND DEFECTS IN SOLIDS | 1995年 / 133卷 / 04期
关键词
ELECTRON PARAMAGNETIC RESONANCE; SUPERPOSITION MODEL; LOCAL CRYSTALLINE ENVIRONMENT; FE3+; LINBO3;
D O I
暂无
中图分类号
TL [原子能技术]; O571 [原子核物理学];
学科分类号
0827 ; 082701 ;
摘要
The substitutions of Fe3+(I) and Fe3+(II) for both Li+ and Nb5+ ions in LiNbO3 crystal have been studied using the superposition model. From the studies, it is found that a displacement of the impurity ion along the c-axis is required to reach a good fit between the calculated andobsrrved zero-field splittings b(2) degrees. By analyzing the displacement direction from the impurity displacement scheme suggested in this paper, we can conclude that Fe3+(I) replaces Li+ ion and Fe3+(II) replaces Nb5+ ion.
引用
收藏
页码:329 / 333
页数:5
相关论文
共 50 条
  • [31] Defect chemistry analysis of the defect structure in Mg-doped LiNbO3 crystals
    Liu, JJ
    Zhang, WL
    Zhang, GY
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1996, 156 (02): : 285 - 291
  • [32] Evolution of defect signatures at ferroelectric domain walls in Mg-doped LiNbO3
    Nataf, Guillaume F.
    Guennou, Mael
    Haussmann, Alexander
    Barrett, Nick
    Kreisel, Jens
    PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2016, 10 (03): : 222 - 226
  • [33] Optical Property of LiNbO3 Crystal Codoped with In, Mg and Fe
    赵业权
    High Technology Letters, 2000, (01) : 61 - 64
  • [34] Sellmeier equation for doubly Er/Mg-doped congruent LiNbO3 crystals
    Zhang, De-Long
    Yang, Qing-Zhong
    Hua, Ping-Rang
    Liu, Hong-Li
    Cui, Yu-Ming
    Sun, Liang
    Xu, Yu-Heng
    Pun, Edwin Yue-Bun
    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 2009, 26 (04) : 620 - 626
  • [35] Green light direct writing of ferroelectric domains in Mg-doped LiNbO3
    Zheng, Shoujun
    Kong, Yongfa
    Zhang, Rong
    Liu, Hongde
    Chen, Shaolin
    Zhang, Ling
    Liu, Shiguo
    Rupp, Romano
    Xu, Jingjun
    OPTICAL MATERIALS EXPRESS, 2014, 4 (02): : 272 - 279
  • [36] Microstructure and characteristics of Zn and Mg-doped LiNbO3 materials for electrochromic devices
    Liu, Haichao
    Gao, Ming
    Zhu, Qinqing
    Chen, Haojie
    Wang, Fangfang
    Zhang, Hu
    CERAMICS INTERNATIONAL, 2025, 51 (02) : 1595 - 1604
  • [37] Raman spectra of crystals LiNbO3:Zn(4.5), LiNbO3:Mg:Fe(5.01, 0.005), LiNbO3:Mg(5.1), and LiNbO3:Mg(5.3 mol %)
    N. V. Sidorov
    A. A. Gabain
    A. A. Yanichev
    I. N. Efremov
    I. V. Biryukova
    M. N. Palatnikov
    Optics and Spectroscopy, 2015, 118 : 269 - 276
  • [38] MECHANISM OF CONDUCTIVITY OF A FE-DOPED LINBO3 CRYSTAL
    BARKAN, IB
    BASKIN, EM
    ENTIN, MV
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1980, 59 (01): : K97 - K102
  • [39] EPR STUDY OF THE 3 FE3+ CENTERS IN LINBO3
    PARK, IW
    CHOH, SH
    SONG, KJ
    YEOM, TH
    RUDOWICZ, C
    JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 1993, 26 (02) : 168 - 171
  • [40] Raman Spectra of Crystals LiNbO3:Zn(4.5), LiNbO3:Mg:Fe(5.01,0.005), LiNbO3:Mg(5.1), and LiNbO3:Mg(5.3 mol %)
    Sidorov, N. V.
    Gabain, A. A.
    Yanichev, A. A.
    Efremov, I. N.
    Biryukova, I. V.
    Palatnikov, M. N.
    OPTICS AND SPECTROSCOPY, 2015, 118 (02) : 269 - 276