(TRIS[4-(2-PYRIDYL)-3-AZA-3-BUTENYL]-AMINE)IRON(II) BIS(HEXAFLUOROPHOSPHATE),[FE(PY(3)TREN)](PF6)(2)

被引：12

作者：

BOUBEKEUR, K ^{[1
]}

DEROCHE, A ^{[1
]}

LAMBERT, F ^{[1
]}

MORGENSTERNBADARAU, I ^{[1
]}

机构：

[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,CHIM BIOORGAN & BIOINORGAN LAB,F-91405 ORSAY,FRANCE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S010827019500597X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination polyhedron of the Fe-II ion in the title compound, [Fe(C24H27N7)](PF6)(2), is best described as a trigonal antiprism twisted 6 degrees towards a trigonal prism. The tris[4-(2-pyridyl)-3-aza-3-butenyl]amine ligand coordinates to the metal centre through the three pyridine and three imino N atoms, each set of atoms forming two parallel ideal equilateral triangles; the metal ion is located between these two planes. The average values for the Fe-N-pyridine and the Fe-N-imino bond lengths are 1.981 and 1.950 Angstrom, respectively. The tripodal bridging amine N atom lies on the pseudo ternary axis of the molecule and is situated 3.427 (7) Angstrom from the Fe centre.

引用

页码：2244 / 2246

页数：3