STEREOSPECIFIC AND REGIOSPECIFIC RING-OPENING OF GLYCIDOL WITH PRIMARY AND SECONDARY ALCOHOLS MEDIATED BY DIISOBUTYLALUMINIUM HYDRIDE

被引：4

作者：

ERUKULLA, RK ^{[1
]}

BYUN, HS ^{[1
]}

LOCKE, DC ^{[1
]}

BITTMAN, R ^{[1
]}

机构：

[1] CUNY QUEENS COLL,DEPT CHEM & BIOCHEM,FLUSHING,NY 11367

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 18期

关键词：

D O I：

10.1039/p19950002199

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Regiospecific ring opening of (R)-(+)- or (S)-(-)-glycidol 1a, b with primary and secondary alcohols in the presence of dusobutylaluminium hydride provides 1-O-alkyl-sn-glycerol 2 without formation of the undesired regioisomer, 2-O-alkylglycerol 3. The configuration of the glycidol is preserved in the product.

引用

页码：2199 / 2200

页数：2

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