GLYCOSYLIDENE CARBENES .9. FULLERENE SUGARS - PREPARATION OF ENANTIOMERICALLY PURE, SPIRO-LINKED C-GLYCOSIDES OF C-60

被引：187

作者：

VASELLA, A ^{[1
]}

UHLMANN, P ^{[1
]}

WALDRAFF, CAA ^{[1
]}

DIEDERICH, F ^{[1
]}

THILGEN, C ^{[1
]}

机构：

[1] SWISS FED INST TECHNOL,ORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 10期

关键词：

D O I：

10.1002/anie.199213881

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sweetened buckyballs are prepared in good yields. The C-glycosylated, uniform, enantiomerically pure C60 mono-addition products 1 (R = benzyl, pivaloyl) are differentiated not only by their chiroptical properties, but also by the conformation of the glycosyl residue, which is dependent on its substituents.

引用

页码：1388 / 1390

页数：3

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