Crystal structure of bis(3-bromomesityl)(quinolin-1-ium-8-yl) boron(III) tribromide

被引：1

作者：

Son, Jungho ^{[1
]}

Tamang, Sem Raj ^{[1
]}

Hoefelmeyer, James D. ^{[1
]}

机构：

[1] Univ S Dakota, Dept Chem, 414 E Clark St, Vermillion, SD 57069 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

基金：

美国国家科学基金会;

关键词：

crystal structure; frustrated Lewis pair; halogen; heterolysis; electrophilic aromatic substitution;

D O I：

10.1107/S2056989015015467

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C27H26.82BBr2.18N+center dot Br-3(-), is a cationic triarylborane isolated as its tribromide salt. The aryl substituents include a protonated 8-quinolyl group and two 3-bromomesityl groups. The molecule was prepared on combination of 3: 1 Br-2 and dimesityl(quinolin-8-yl) borane in hexanes. The refinement of the structure indicated a degree of 'over-bromination' (beyond two bromine atoms) for the cation. There are two tribromide ions in the asymmetric unit, both completed by crystallographic inversion symmetry.

引用

页码：1114 / +

页数：9