Convection and thermal diffusion in a solution heated from below II. The system CHBr2 center dot CHBr2-CHCl2 center dot CHCl2

被引:28
作者
Legros, J. C.
Van Hook, W. A. [1 ]
Thomaes, G.
机构
[1] Univ Libre Bruxelles, Brussels, Belgium
[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
关键词
D O I
10.1016/0009-2614(68)85014-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The critical point for the onset of convection (Benard point) was determined for the system CHBr2 center dot CHBr2 - CHCl2 center dot CHCl2. No stabilizing effect was observed. Experiments which sampled this and a conventional thermal diffusion cell (cf. following letter) to directly measure the concentration gradient due to thermal diffusion revealed that the gradient was destroyed when the solution is heated from below. This is an unexpected and important observation.
引用
收藏
页码:249 / 250
页数:2
相关论文
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