METHYLTIN AND METHYLINDIUM BIS(TRIMETHYLSILYL)AMIDES

被引：0
作者：
RANNENBERG, M
WEIDLEIN, J
OBERMEYER, A
机构：
[1] UNIV STUTTGART,INST ANORGAN CHEM,PFAFFENWALDRING 55,W-7000 STUTTGART 80,GERMANY
[2] MAX PLANCK INST FESTKORPERFORSCH,W-7000 STUTTGART 80,GERMANY
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 04期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
BrSn[N(SiMe3)2]3 and ClIn[N(SiMe3)2]2 react with LiMe.O(C2H5)2 (Me = CH3) in toluene or hexane to give the corresponding amido derivatives MeM[N(SiMe3)2]x (M = Sn, x = 3 and M = In, x = 2). These new compounds and the other members of the homologous series Me(n)M[N(SiMe3)2]4 or 3-n are characterized by their IR, Raman und NMR spectra. In addition, the results of the crystal structure determination of MeSn[N(SiMe3)2]3 are reported.
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页码：459 / 467
页数：9
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