SYNTHESIS OF N-ALKYL-SUBSTITUTED PERYLENES AND TERRYLENES VIA ALKALI-METAL INDUCED CYCLIZATION OF OLIGONAPHTHYLENES

被引：27

作者：

ANTON, U ^{[1
]}

GOLTNER, C ^{[1
]}

MULLEN, K ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES,ACKERMANNWEG 10,W-6500 MAINZ,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 10期

关键词：

PERYLENE; TERRYLENE; BAY-SUBSTITUTION; STERIC STRAIN;

D O I：

10.1002/cber.19921251021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of two novel n-alkyl- or aryl-substituted perylenes and of an n-alkylated terrylene is possible by an alkali-metal induced cyclization of the corresponding bi- or trinaphthyls. Differences in reactivity of the naphthylenes in the ring-closure reaction are caused by the different substitution pattern. UV and fluorescence spectra as well as the Stability of the resulting rylenes[2] are discussed as a function of substitution.

引用

页码：2325 / 2330

页数：6

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