SYNTHESIS AND X-RAY STRUCTURE OF SELENASAPPHYRIN

被引：44

作者：

LISOWSKI, J ^{[1
]}

SESSLER, JL ^{[1
]}

LYNCH, V ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 13期

关键词：

D O I：

10.1021/ic00117a032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a new sapphyrin macrocycle, selenasapphyrin, with one of the nitrogen atoms in the inner core replaced by a selenium atom is described. This macrocycle is able to bind anions when protonated and form out-of-plane complexes with certain low-valent transition metal fragments once deprotonated. These chemical properties were confirmed by X-ray diffraction analysis with structures of both the bis(hydrochloride) salt and bis(iridium(I) dicarbonyl) complex being obtained.

引用

页码：3567 / 3572

页数：6

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