INTERFACE PROPERTIES OF BLENDS OF INCOMPATIBLE POLYMERS

被引：31

作者：

GUCKENBIEHL, B ^{[1
]}

STAMM, M ^{[1
]}

SPRINGER, T ^{[1
]}

机构：

[1] FORSCHUNGSZENTRUM JULICH, D-52425 JULICH, GERMANY

来源：

PHYSICA B-CONDENSED MATTER | 1994年 / 198卷 / 1-3期

关键词：

D O I：

10.1016/0921-4526(94)90141-4

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Neutron reflectometry is used to study the interface in blends of the partially compatible polymers deuterated polystyrene (PSd) and poly(styrene-co-4-bromo-styrene) (PBr(x)S). The degree of bromination x controls the miscibility of the polymers. It is varied in a wide range in order to obtain information on the dependence of the interface width l on the compatibility of the components as expressed by the Flory Huggins interaction parameter chi. The kinetics of interface formation and the equilibrium values of l and chi as a function of bromination are discussed and compared to current theories.

引用

页码：127 / 130

页数：4

共 11 条

[1] COLLECTIVE DIFFUSION, NUCLEATION, AND SPINODAL DECOMPOSITION IN POLYMER MIXTURES [J].