ALKALI-METAL SALTS OF PERFLUORINATED COMPLEX ANIONS - EFFECTIVE REAGENTS FOR NUCLEOPHILIC FLUORINATION

被引:22
|
作者
FAROOQ, O
TIERS, GVD
机构
[1] Graphic Research & Science Research Laboratories, 3M Central Research, St. Paul, Minnesota 55144
来源
JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 08期
关键词
D O I
10.1021/jo00087a031
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Alkali metal salts:of perfluorinated complex anions were used to effect halogen-exchange fluorination in organohalosilanes both in the presence and absence of solvent. By the use of salts of perfluorinated ''non-nucleophilic'' anions in a high-boiling multifunctional etheral solvent, organofluorosilanes have been conveniently prepared in high yields.
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页码:2122 / 2124
页数:3
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