ZN(++)-COMPLEXES AS MODELS OF METALLOENZYMES IN MICELLAR ESTEROLYSIS - LIGAND STRUCTURE-DEPENDENT STOICHIOMETRY OF THE COMPLEXES

被引：9

作者：

FAIVRE, V

BREMBILLA, A

ROIZARD, D

LOCHON, P

机构：

[1] Laboratoire de Chimie-Physique Macromoléculaire associé au CNRS, Ecole Nationale Supérieure des Industries Chimiques, 54001 Nancy, 1 rue Grandville

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 02期

关键词：

D O I：

10.1016/0040-4039(91)80852-W

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lipophilic 2-hydroxymethylbenzimidazoles complexed by Zn++ ions were investigated for their esterolytic activities in the hydrolysis of p-nitrophenyl picolinate in the presence of cationic micelles. The nature and the stoichiometry of the active complexes 1:1 or 2:1 types were shown to be dependent on the position of the substituant on the heterocycle and on the surfactant concentration.

引用

页码：193 / 196

页数：4

共 6 条

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