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- [21] SEEBACH D, 1969, SYNTHESIS-STUTTGART, P17, DOI DOI 10.1055/S-1969-34190
ONE-STEP SYNTHESIS OF COMPLEX CYCLOPROPANONE PHENYLTHIOKETALS BY THE REACTION OF SULFUR-STABILIZED ANIONS WITH KETENE BIS(PHENYLTHIO)ACETAL
被引：20
作者：
COHEN, T
WEISENFELD, RB
GAPINSKI, RE
机构：
[1] Department of Chemistry, University of Pittsburgh, Pittsburgh
关键词：
D O I：
10.1021/jo00393a071
中图分类号：
O62 [有机化学];
学科分类号：
070303 ;
081704 ;
摘要：
Organolithium compounds which are stabilized by a phenylthio group lose the latter and form cyclopropanone phenylthioketals upon reaction with 1, 1-bis-(phenylthio)ethene; the latter is prepared by copper(I)-induced elimination of thiophenol from 1, 1, 1-tris(phenylthio) ethane, which is in turn generated by the reaction of acetic acid with a reagent formed by the reaction of trimethylaluminum with thiophenol. © 1979, American Chemical Society. All rights reserved.
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页码：4744 / 4746
页数：3
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