RELATIVISTIC CORRECTIONS TO THE ATOMIC ELECTRON-AFFINITIES

被引:18
|
作者
DELAVEGA, JMG [1 ]
机构
[1] UNIV AUTONOMA MADRID, FAC CIENCIAS, DEPT QUIM FIS APLICADA, E-28049 MADRID, SPAIN
来源
PHYSICAL REVIEW A | 1995年 / 51卷 / 03期
关键词
D O I
10.1103/PhysRevA.51.2616
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The effect of relativistic corrections in the electron affinities (Ae) of the atoms (Li through I) has been determined. The relativistic contributions to the Ae are negative, except for Cu, Rh, and Ag atoms and are large for some transition-metal atoms. The values of the corrected Ae have been used in order to estimate the contribution of the correlation energies to the Ae. © 1995 The American Physical Society.
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页码:2616 / 2618
页数:3
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