MICROWAVE DIELECTRIC LOSS IN POLYCRYSTALLINE 3D METAL-COMPLEXES

被引：6

作者：

SHAIKHUTDINOV, SK ^{[1
]}

SHUPIK, AN ^{[1
]}

TRUKHAN, EM ^{[1
]}

机构：

[1] MOSCOW PHYS TECH INST,DOLGOPRUDNYI,RUSSIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1993年 / 89卷 / 21期

关键词：

D O I：

10.1039/ft9938903959

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Some polycrystalline 3d metal complexes including tris(acetylacetonato)metal(III) complexes and bis-N-substituted salicylidenamines copper(II) complexes and their derivatives have been investigated by the microwave dielectric loss method. The correlation between the dielectric losses and electronic structure of the coordination centre has been observed. Its mechanism seems to be due to an intramolecular polarization of the coordination centre.

引用

页码：3959 / 3962

页数：4

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