CHIRAL, CYCLIC AMINO ALDEHYDES IN THE BAYLIS-HILLMAN REACTION - A ROUTE TO SPHINGOSINE ANALOGS

被引：34

作者：

DREWES, SE

KHAN, AA

ROWLAND, K

机构：

[1] Department of Chemistry, University of Natal, Pietermaritzburg

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 02期

关键词：

D O I：

10.1080/00397919308009766

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(L)-Serine and (S)-prolinol, after suitable protection and transformations, react smoothly with methyl acrylate and DABCO (Baylis-Hillman reaction). The product from the (L)-serine reaction can be regarded as an analogue of sphingosine.

引用

页码：183 / 188

页数：6

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