KINETICS OF DEPOSIT FORMATION FROM HYDROCARBONS - FUEL COMPOSITION STUDIES

被引：28

作者：

TAYLOR, WF

机构：

[1] Government Research Laboratory, Esso Research and Engineering Co., Linden

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT | 1969年 / 8卷 / 04期

关键词：

D O I：

10.1021/i360032a008

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

To elucidate the effect of hydrocarbon fuel composition on autoxidative deposit formation, the deposit formation tendency of various pure hydrocarbons and binary blends was studied from 200° to 450° F. in the presence of air. The deposit formation tendency of normal paraffins varies with carbon number. For a given carbon number branched paraffins are more deleterious than normal paraffins. The presence of an aromatic or naphthene in a binary blend with a paraffin inhibits deposit formation, particularly at lower concentrations and temperatures. Although olefins in general are deleterious toward deposit formation, the effect of individual olefins varies widely. Deposit formation results are compared with oxidation and cooxidation kinetic studies. © 1969, American Chemical Society. All rights reserved.

引用

页码：375 / &

共 14 条

[1]

ALAGY J, 1959, B SOC CHIM FR, P1325

[2]

ALAGY J, 1961, B SOC CHIM FR, P1792

[3]

CHURCHILL AV, 1966, SAE T, V74, P641

[4]

Ingold KU, 1967, 7 WORLD PETR C MEX C

[5] FREE-RADICAL AUTOXIDATIONS OF HYDROCARBONS [J].