SILYLENE CHEMISTRY .2. A KINETIC STUDY OF THERMOLYSIS OF SYM-DIMETHOXY-TETRAMETHYLDISILANE

被引：26

作者：

ATWELL, WH

MAHONE, LG

HAYES, SF

UHLMANN, JG

机构：

[1] Organometallic and Inorganic Research Laboratories Dow Corning Corporation, Midland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 18卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)80234-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A detailed kinetic study of the thermolysis of sym-dimethoxytetramethyldisilane (I) has been carried out. This study provides strong support for our previous proposal that dimethyldimethoxysilane and dimethylsilylene are formed in an unimolecular and rate determining a-elimination step. Further, chemical evidence is reported which, for the first time, clearly and unambiguously demonstrates insertion of silylenes into the silicon-oxygen bond of alkoxysilanes. © 1969.

引用

页码：69 / &