ELECTROACTIVE POLY(ARYLENE SULFIDE) - ELECTRO-OXIDATIVE POLYMERIZATION OF 3,5-DIMETHYLTHIOPHENOL

被引:7
作者
YAMAMOTO, K [1 ]
IWASAKI, N [1 ]
NISHIDE, H [1 ]
TSUCHIDA, E [1 ]
机构
[1] WASEDA UNIV,DEPT POLYMER CHEM,TOKYO 169,JAPAN
关键词
D O I
10.1016/0014-3057(92)90251-V
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
3,5-Dimethylthiophenol and bis(3,5-dimethylphenyl) disulphide have been electro-oxidatively polymerized to poly(2,6-dimethylphenylene sulphide) under mild conditions. The polymer film formed on the electrode has a semi-conductivity of 10(-9) S/cm and electrochemical response. Its redox potential at 1.3 V corresponds to a doping-dedoping reaction.
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页码:341 / 346
页数:6
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