STEREOSELECTIVE SYNTHESIS OF OPTICALLY-ACTIVE ALPHA-METHYL ESTERS

被引：13
|
作者：
PETIT, Y
SANNER, C
LARCHEVEQUE, M
机构：
[1] Laboratoire de chimie associ, 'e au CNRS, Ecole Normale Supérieure, 75231 Paris Cedex 05
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 15期
关键词：
D O I：
10.1016/0040-4039(90)80095-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Trifluoromethanesulfonic esters of α-hydroxyesters which are easily available from the corresponding esters and triflic anhydride react with lithium dimethylcuprate in ether or magnesiocuprates in THF to provide α-methyl esters in high enantiomerical purity. © 1990.
引用
收藏
页码：2149 / 2152
页数：4
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